http://leah4sci.com/syllabus Presents: Pencil Trick for Ranking 1, 2, 3, and 4 Carbons, Radicals, Amines, Alcohols and other AtomsWatch Next: General Chemistry Review for Organic Chemistry Students https://youtu.be/PRbercrBTos Need help with Orgo? Primary carbon atom means that only one of the bonds is another carbon . If a carbon atom attached to functional group is directly attached to only one carbon atom, then it is said to be a "primary carbon atom" or, Secondary carbon atom. Journey of a carbon atom - Understanding Evolution For example, butane has two primary carbon atoms. A primary alcohol is an alcohol with a primary carbon atom and a hydroxyl group. One day the Little Carbon Atom was minding his own . What is the meaning of primary carbon? When the hydroxyl group is bonded directly to a benzene ring, the compound is classified as a phenol. [1] It is thus at the end of a carbon chain. ). Structure of Alcohol: Classification, Formula - Embibe Carbon in its diamond form is used in jewellery. 3. Step 3 Tertiary carbon atoms can occur for example in branched alkanes but not in linear alkanes. How do you know if a carbon is primary secondary - Studybuff Check 'primary carbon atom' translations into Tamil. Structural formula of isobutane (tertiary carbon is highlighted red ) A tertiary carbon atom is a carbon atom bound to three other carbon atoms. Few examples of tertiary carbonation are given . For aromatic nitro compounds prefixes o-(for 1,2), m-(for1,3) and p-(for 1,4 . Carbon usually has a valence of +4, which means each carbon atom can form covalent bonds with four other atoms. For instance, when the carbon atoms in an ethane molecule (CH 3 -CH 3) are both bonded to one another, they are both the primary carbon atoms. Related Articles: Intermolecular forces in hydrogen sulfide? They are represented by the general formula R - 1 CH 2 - X. [2], https://en.wikipedia.org/w/index.php?title=Primary_carbon&oldid=956016011, Creative Commons Attribution-ShareAlike License 3.0, This page was last edited on 11 May 2020, at 02:32. Difference Between Primary and Secondary Allylic Carbocations Carbon atoms make four bonds. metric tons of CO have been released worldwide due to burning fossil fuels. It makes up for 18% of the human body. So it would make sense that carbocation become more stable as you increase the number of electrons donating groups attached to them. The carbonyl group is composed of a carbon atom double-bonded to an oxygen atom. Diamonds are made of carbon. Tertiary Carbocation > Secondary Carbocation > Primary Carbocation. This molecule is called 2-methylpropane. What is carbon and example? - Reimagining Education Usually, they form as an intermediate during various chemical reactions. Carbon atoms comprise a nucleus of neutrons and six protons surrounded by six electrons. Definition of sp3 Carbon | CurlyArrows Chemistry Tutorials Chemical Reactions - Description, Concepts, Types, Examples and FAQs, Annealing - Explanation, Types, Simulation and FAQs, Classification of Drugs Based on Pharmacological Effect, Drug Action, Uses of Rayon - Meaning, Properties, Sources, and FAQs, Reverberatory Furnace - History, Construction, Operation, Advantages and Disadvantages, 118 Elements and Their Symbols and Atomic Numbers, Nomenclature of Elements with Atomic Number above 100, The double-bonded carbon atoms are further classified as vinylic and allylic carbon atoms. carbon (C), nonmetallic chemical element in Group 14 (IVa) of the periodic table. Because of its tetravalency, carbon exhibits catenation and can form different organic compounds. Carbon is also found in soil from dead and decaying animals and animal waste. The carbon atom at each end of a carbon chain is primary. For example, propane has two primary carbon atoms and a secondary carbon atom. Turn on. Some examples of these primary alcohols include Methanol (propanol), ethanol, etc. The general chemical formula for the vinyl group is R-CH=CH2, where both the carbon atoms are bonded with a double bond, and R is attached at the vinylic position. There are three common naturally occurring forms of carbon: graphite, amorphous carbon, and diamond. We can denote them as 1 0 haloalkanes. Primary vs Secondary ZDDP | Bob Is The Oil Guy hybridized. If a secondary carbon atom is bonded to the hydroxyl group, the alcohol is called secondary alcohol. We also acknowledge previous National Science Foundation support under grant numbers 1246120, 1525057, and 1413739. The non-metals are electronegative in nature, unlike metals. However, the middle carbon (CH 2) is connected to two carbon atoms, therefore it is a secondary carbon. Explanation: Reactivity order for the alkyl halides towards Sn2 reaction is R-I>R-Br>R-Cl>R-F. Legal. This can be explained by which halogen atom is a better leaving group compared to the other. Sugar, glucose, proteins etc are all made of it. Carbon is an essential element for all life forms on Earth. A carbon atom bonded to only one other carbon atom isa primary carbon atom designated by the symbol 1. How do you know if a carbon is primary secondary or tertiary? The general chemical formula for the vinyl group is R-CH=CH. Primary carbocations Ethane (C 2 H 6), butane (C 4 H 10), and propane (C 3 H 8) are some other common examples of hydrocarbons. What is carbon and example? A primary carbon is a carbon atom which is bound to only one other carbon atom. The carbon atom at each end of a carbon chain is primary. This allows for an easy description of branching in alkanes. Such elements are called metalloids and are located in between metals and non-metals in the form of a zig-zag line. Pencil Trick for Primary, Secondary, Tertiary, & Quaternary Carbon and How do you identify a primary carbon? It is a basic of all other organic compounds. Carbon is used in some way in most every industry in the world. Graphite is used as the lead in your pencils. What are 6 ways to prevent infectious diseases? A primary alcohol is an alcohol which has the hydroxyl group connected to a primary carbon atom. Answer (1 of 2): Yes, I can. For example, in the ethane molecule (CH3-CH3), both the carbon atoms are bonded with one other carbon atoms. This organic chemistry video tutorial explains how to identify primary, secondary, tertiary hydrogen atoms and quarternary carbon atoms as well as for alkyl . Stability of carbocation intermediates. For example, in propene, the highlighted atom is the allylic carbon atom (CH3-CH=CH2). Most of the atom is empty space. An example of carbon is a basic matter found in dinosaur bones which is used to determine the age of the bone. S. . As such, the atom is the basic building block of chemistry. Other elements such as hydrogen, nitrogen, oxygen etc. . In chemistry, a primary carbon atom is one that is bonded to another carbon atom. Score: 4.8/5 (48 votes) . What Is A Primary Carbon - Micro B Life What are the diagnostic techniques for infectious agents? Some examples of primary halides are: How do you identify a primary carbon? . They are among the hardest of materials and are used to cut glass and steel. carbon atom in a sentence | Sentence examples by Cambridge Dictionary The rate of this step - and therefore, the rate of the overall substitution reaction - depends on the activation energy for the process in which the bond between the carbon and the leaving group breaks and a carbocation forms. What is the meaning of primary carbon atom in Chinese and how to say primary carbon atom in Chinese? What are three ways to get an infectious disease? The allylic carbocation is stable because of the delocalization of electrons on carbon atoms. If the allylic carbon atom is associated with one carbon atom carrying a +1 charge, it is referred to as a primary allylic carbocation. Therefore, the general structure of a primary halogenoalkanes is R-CH 2 -X; R is an alkyl group while X is a halogen. How is bird like a vultures important to ecosystem? Arrange the following carbocations in decreasing order of stability? Carbocation Structure and Stability | MCC Organic Chemistry It is used to make all sorts of materials including plastics and alloys such as steel (a combination of carbon and iron). A day in the life of a Carbon atom - St Michael's Catholic Primary Skip to . Example, \ ( {\rm He lived a happy life. Examples of primary alcohols include ethanol and butanol. Carbocation - Definition, Types, Formation, Order and Stability - BYJUS X can be fluorine (F), chlorine (Cl), bromine (Br) or iodine (I). 1 degree or primary carbon atom are those carbon atom in which only one valency of carbon atom is satisfied by another carbon atom and other are satisfied by any different element e.g. Since both the carbon atoms form a double covalent bond, so both of them are sp. The carbon atom at each end of a carbon chain is primary. Most carbon is stored in reservoirs, or sinks, such as rocks and sediments, while the rest is stored in the atmosphere, oceans, and living organisms. The oxygen atom forms one sigma bond and one pi bond with the carbon atom. carbocations (or carbonium ions) - chemguide , where both the carbon atoms are bonded with a double bond, and R is attached at the vinylic position. A primary (1) carbon is a saturated carbon in an organic species bonded to only one carbon atom, eg: see also secondary carbon, tertiary carbon, quaternary carbon Carbon is in a constant state of movement from place to place. A tertiary carbon written as 3 (#3 with a degree symbol) is a carbon attached to three other carbons. Carbon is a chemical element with symbol C and atomic number 6. Classified as a nonmetal, Carbon is a solid at room temperature. The LibreTexts libraries arePowered by NICE CXone Expertand are supported by the Department of Education Open Textbook Pilot Project, the UC Davis Office of the Provost, the UC Davis Library, the California State University Affordable Learning Solutions Program, and Merlot. A Day in the Life of a Carbon Atom Year 6/7 St. Michael's Catholic Primary School 2012 Starring: Adom. Step 2 2 of 4. a) In this example, we should draw a structure that has nine primary hydrogens. Inorganic carbon sources include carbon dioxide, limestone, and dolomite. Three isotopes of carbon occur naturally. How are parts of the ecosystem connected? A carbon atom that is bonded with one other carbon atom is called a primary carbon atom. It is also released by burning materials such as wood, oil and gas. If a carbon attached to functional group is directly attached to the two C-atoms, then it . If this carbon is bonded to two other carbons, it is a secondary (2 o) alcohol. The top 4 are: carbon atom, carbon-carbon bond, alkane and carbon chain.You can get the definition(s) of a word in the list below by tapping the question-mark icon next to it. Primary and methyl carbocations especially are seen rarely in organic reactions except under special circumstances such as in the case of benzylic or allylic cations. A secondary carbon written as 2 (#2 with a degree symbol) is a carbon attached to two other carbons. For example, the carbon atom marked with an asterisk (*) in ethyl alcohol, is attached to two substituents (CH 3 and OH), yet it is regarded as a primary carbon atom. Tens of millions of artificial carbon compounds are useful for petroleum (gasoline) and plastics. Different events can convert carbon atoms Jennifer's research highlights how carbon atoms move through living things, the atmosphere, and the Earth over tremendously long periods of time. However there are important differences in the structures of various types of carbocations. If a primary carbon atom is bonded to the hydroxyl group, the alcohol is called primary alcohol. 2-Bromobutane is relatively stable, but is toxic and flammable. Is methyl a primary alkyl halide? - Studybuff Carbon can exist in many different forms: as part of a carbon dioxide molecule, as coal, or as part of the body of a living organism, for example. The definition given above makes this classification obvious: the carbon atom in question is directly bonded to only one other carbon atom. Alkyl groups are a perfect example. How are human activities contributing to global warming Brainly? with the carbon atom bearing the nitro group getting the lowest possible number. The halogen group is attached to the carbon atom that has only one neighbouring alkyl group. Discovered: First isolated by H. Moissan in 1886 after 74 years of efforts by various investigators (The unknown element had been observed as a constituent of minerals.). If the halide (X) group is attached to a primary carbon atom or \(1^{\circ}\) carbon atom, which is bonded to only one other carbon atom, then the compound is a primary halide. Types Of Carbon Atoms - TyroCity Ut enim ad minim. Example, carbon of an alkane or an alkyl group. A primary carbon atom contains only one aryl or alkyl group attached to it while other bonds are C-H bonds. The tertiary carbocation is the most stable one, as it is surrounded by other three carbon atoms that share its positive charge burden. Typical example of primary carbon atoms are the / the terminal (s) carbon atom (s) in ethane or chloromethane. Since the formal charge of +1 is on primary carbon atom here, it is named as primary allylic carbocation. We know that the rate-limiting step of an S N 1 reaction is the first step - formation of the this carbocation intermediate. What are primary secondary and tertiary halides? How is carbon used today? For example, 1-methyl-1-isopropyl-cyclopropane meets these criteria, as do any of the homologous gem-disubstituted cycloalkanes. There once was a Little Carbon Atom, who lived peacefully under the ground. Aliphatic Hydrocarbons: The hydrocarbons in which carbon atoms are joined form an open chain are called aliphatic hydrocarbons. The words at the top of the list are the ones most associated with primary carbon atom, and as you go down the relatedness . Inorganic Chemistry In Inorganic Chemistry a description of salts are formed by neutralization of a hydroxy group of a polybasic acid, such as calcium dihydrogen phosphate, Ca ( H2PO4 ) 2 . So, both carbon atoms are the primary carbon atom here. Likewise, in cyclohexene, the carbon atoms that are next to the double bond are known as the allylic carbon atoms. primary carbon atom in Tamil - English-Tamil Dictionary | Glosbe Ouellette 2/e p 219. 1. A primary carbon can be written as 1 (#1 with a degree symbol) has one carbon attached to this carbon atom. How do you know if a carbon is primary secondary or tertiary? If there is a formal charge of +1 on the secondary carbon inside the more strong of two allyl carbocation resonance groups, the allyl carbocation is referred to as secondary (2) allyl carbocation; if there is a formal charge of +1 on the secondary carbon in each resonance carbocation, it is also referred to as secondary allyl carbocation. A few elements show the intermediate properties of metals and non-metals. Both compounds share the molecular formula C 4 H 9 Br. A primary carbon is a carbon atom which is bound to only one other carbon atom. Example: . Primary, secondary, tertiary carbons - ChemistryScore It is used for fuel in the form of coal, methane gas, and crude oil (which is used to make gasoline). For this reason tertiary carbon atoms are found only in hydrocarbons containing at least four carbon atoms. what is a primary carbon - answers from professionals Also, we will find that the number of carbons attached to a given atom will have subtle effects on its chemistry. 20 examples: The hybrid was of two different kinds of orbitals combined to produce the The allylic carbon atoms are sp3 hybridized carbon atoms in the allylic group, RCH2-CH=CH2, that is bonded with the -CH=CH2 group. Links \u0026 Resources Mentioned In This Video:Carbocation Stability Tutorial: http://leah4sci.com/carbocation-stability-and-ranking/Formal Charge Formula Shortcut Video: http://leah4sci.com/formal10 Secrets to Acing Organic Chemistry: http://leah4sci.com/orgo-ebook/For more in-depth review including practice problems and explanations, come join my online membership site the organic chemistry study hall: http://leah4sci.com/joinFor private online tutoring visit my website: http://leah4sci.com/organic-chemistryFinally, for questions and comments, find me on social media here:Facebook: https://www.facebook.com/Leah4SciTwitter: https://twitter.com/Leah4SciInstagram: https://www.instagram.com/leah4sci/Google+ : https://plus.google.com/u/0/+LeahFischPinterest: http://www.pinterest.com/leah4sci/ Can you draw a structural formula for a hydrocarbon that has 3 primary It is bonded to a carbon atom that is bonded doubly to another carbon atom. sacrifice itself) for maximum wear protection. Hydrohalogenation involves the addition of a hydrogen atom and a halogen atom to an unsaturated compound (containing a carbon-carbon double bond). (1) Primary (1) alkyl halide : Alkyl halide in which a halogen atom is bonded to a primary carbon atom is called primary alkyl halide. CBSE Previous Year Question Paper for Class 10, CBSE Previous Year Question Paper for Class 12. eiusmod tempor incididunt ut labore et dolore magna aliqua. Primary (1) carbon atom - bonded to one other carbon atom, Secondary (2) carbon atom - bonded to two other carbon atoms, Tertiary (3) carbon atom - bonded to three other carbon atoms, Quaternary (4) carbon atom - bonded to four other carbon atoms. So far you have learned that: The carbonyl group is a functional group with the general formula C=O that is attacked by nucleophiles. What are primary, secondary and tertiary carbons? - StudyOrgo.com Most carbon is stored in reservoirs, or sinks, such as rocks and sediments, while the rest is stored in the atmosphere, oceans, and living organisms. Terms: Primary, Secondary, Tertiary, Quaternary - b Bruner 2. [1] It is thus at the end of a carbon chain. In case of an alkane, three hydrogen atoms are bound to a primary carbon (see propane in the figure on the right). The complexity of this alkyl chain is unrelated to the classification of any alcohol considered as primary. Types of Carbon Atoms: Primary Carbon Atom: Carbon atom which is attached to only one other or no carbon atom is called primary carbon. A carbon atom bonded to only one other carbon atom is a primary carbon atom designated by the symbol 1. Likewise, in the carbocation of cyclohexene case, the formal charge on allylic carbon is +1, and it stabilizes by resonance with a pi-bond. the next time we use these terms is for amines, and that is a quite different story. ), both the carbon atoms are bonded with one other carbon atoms. The rest consists of a positively charged nucleus of protons and neutrons surrounded by a . Alcohols are organic compounds that contain one or more hydroxy (- OH) groups attached to a carbon atom of an alkyl group or a hydrocarbon chain. Secondary alcohol has the hydroxyl group on a secondary \(\left({{2^ \circ }} \right)\) carbon atom bonded to two other carbon atoms. The allylic position is also similar to a vinylic position. If the carbon is primary (\({1^ \circ },\) bonded to only one other carbon atom), the compound is a primary alcohol. For example, in the ethane molecule (CH3-CH3), both the carbon atoms are bonded with one other carbon atoms. Rearrangements (Hydride Shift) - Learn Chemistry Online | ChemistryScore As the +I affects the increases of the positively charged carbon atom of the carbocation, it reduces the positive charge that exists on the carbocation. don't count. What scale is used to measure heat waves? Carbon gets its name from the Latin word carbo, which means coal. Diamonds and graphite are among the hardest and softest natural materials known, respectively. What Is A Primary Carbon - Realonomics Carbon is found in the biosphere stored in plants and trees. A primary (1) carbon is a saturated carbon in an organic species bonded to only one carbon atom, eg: see also secondary carbon, tertiary carbon, quaternary carbon. Primary carbon - Wikipedia For example butane has two primary carbon atoms. The stability of the carbocations is determined by the steric hindrance and +I effect of alkyl groups attached to C+ of the carbocation. Primary carbon atom. This page titled Primary Carbon is shared under a All Rights Reserved (used with permission) license and was authored, remixed, and/or curated by Gamini Gunawardena via source content that was edited to the style and standards of the LibreTexts platform; a detailed edit history is available upon request. The general formula of allyl is given as - R-CH2-CH=CH2, where the asterisk carbon atom is an allylic carbon atom. In organic chemistry, a vinyl halide is a compound with the formula CH2=CHX (X = halide). Carbon is also found in fossil fuels, such as petroleum (crude oil), coal, and natural gas. Typically, a neutral carbon atom forms four covalent bonds, and one covalent bond is removed when it forms a cation. Carbons have a special terminology to describe how many other carbons they are attached to. Allylic Carbon - Meaning, Atomic Structure and Hydrocarbons - VEDANTU Explain the Factors Affecting the Stability of Carbocation? Classification of Haloalkanes and Haloarenes - Embibe Below is a list of primary carbon atom words - that is, words related to primary carbon atom. Generally, carbocations are unstable due to not having eight electrons to satisfy the octet rule. An example is given in the figure below. . Carbon is used in some way in most every industry in the world. CH3-CH3 in ethane both carbon atom are primary carbon atom. An sp 3 carbon depending on the number and the type of neighbor can be further be classified as primary (1 o), secondary (2 o), tertiary (3 o), quaternary (4 o), allylic . But caution. WikiMatrix. Examples Add . Explain Primary, Secondary, and Tertiary Allylic Carbocations? It is . All carbocations (previously known as carbonium ions) carry a positive charge on a carbon atom. Natural gas and crude oil both contain hydrocarbons. Step #1: Pick a carbon Step #2: Count how many carbons are directly attached to it. Based on the carbon atoms bonding count with a carbon atom, we can classify these as primary, secondary, and tertiary carbon atoms. What is the difference between a disease and an infectious disease? Although widely distributed in nature, carbon is not particularly plentifulit makes up only about 0.025 percent of Earths crustyet it forms more compounds than all the other elements combined. 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MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkylborane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Carbanion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkyl_sulfonate : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkynyl_carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkynyl_group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkynyl_halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alkynyl_hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Allylic_Substitution : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Amino_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Anomer : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Cleavage : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Alpha_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Ambident_Nucleophile : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amide_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amine : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amine_Oxide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amino_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amino_Acid_Residue : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amino_Acid_Unit : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Ammonium_Ion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Amphoteric : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anchimeric_Assistance : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Angle_Strain : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anhydride : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Annulene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anomeric_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anomeric_Center : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anomers : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Anti-Markovnikov_Addition" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiaromatic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiaromatic_Annulene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiaromatic_Compound : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anticoplanar : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiparallel : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Antiperiplanar : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anti_Addition : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Anti_Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aprotic_Solvent : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Arene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Arenesulfonic_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Arenium_Ion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Amine : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Annulene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Compound : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Ether : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Hydrocarbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aromatic_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Carbanion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Ester : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryl_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Aryne : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Assisted_Homolysis : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Asymmetric_Carbon_Atom : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Autoxidation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Axial_Bond : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", A_Value : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Baeyer-Villiger_Oxidation" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Base : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Base_Peak : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Base_Strength : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beckmann_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Beer-Lambert_Law" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzene_Ring : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzilic_Acid_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzylic_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzylic_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzylic_Halide : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzylic_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzyl_Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzyl_Radical : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzyne : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Benzyne_Mechanism : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Betaine : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Amino_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Anomer : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Cleavage : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Beta_Hydrogen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bicycloalkane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Birch_Reduction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Boat_Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bond_Angle : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bond_Axis : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bond_Dissociation_Energy : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Branched_Alkane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bridge : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bridged_Bicycloalkane : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bridgehead_Carbon_Atom : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Brnsted-Lowry_Theory" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Bromohydrin : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "C-Terminal" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Cahn-Ingold-Prelog_Convention" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbanion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbanion_Equivalent : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbene_Equivalent : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbenoid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbocation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbocation_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbocycle : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbohydrate : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbonyl_Carbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbonyl_Compound : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbonyl_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carbonyl_Oxygen : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylate_Ion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Anhydride : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Derivative : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Ester : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Ester_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Group : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Carboxylic_Acid_Salt : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Catalytic_Hydrogenation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Catalytic_Reduction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Center_of_Chirality : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", CFB : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chair_Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chemically_Equivalent_Ligands : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chemical_Ionization : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chemical_Shift : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chemoselective : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chirality_Center : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chiral_Atom : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chiral_Center : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chiral_Molecule : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chlorofluorocarbon : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chlorohydrin : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chromate_Ester : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Chromic_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", CIP_Convention : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", "Cis-Trans_Isomers" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Claisen_Condensation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Claisen_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Clemmensen_Reduction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Combustion : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Concerted_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Condensation_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Configuration : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conformation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conformer : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugated_Diene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugated_Double_Bond : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugate_Acid : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugate_Addition : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Conjugate_Base : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Constitutionally_Heterotopic : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Constitutional_Isomers : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Coordination_Number : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Cope_Elimination : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Cope_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Cope_Rearrangement : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Coupling : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Coupling_Constant : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Coupling_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Crossed_Aldol_Condensation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Crossed_Aldol_Reaction : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Crossed_Claisen_Condensation : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Crosslink : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Crown_Ether : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Cumulene : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.b__1]()", Curved_Arrow : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass226_0.